Acid rain is caused by the pollution of environment by

Updated 11 Apr 2026

Contents12
UPSC Prelims GS2013Environment
  1. Acarbon dioxide and nitrogen
  2. Bcarbon monoxide and carbon dioxide
  3. Cozone and carbon dioxide
  4. Dnitrous oxide and sulphur dioxide
Show answer

Answer: (D) nitrous oxide and sulphur dioxide

Acid rain is caused primarily by two pollutants:

Sulphur dioxide (SO₂) and Nitrogen oxides (NOₓ — including nitrous oxide/N₂O and nitrogen dioxide/NO₂).

These gases are released mainly by burning fossil fuels (coal, petroleum) in power plants, vehicles, and industries.

When SO₂ and NOₓ rise into the atmosphere, they react with water vapour, oxygen, and other chemicals to form sulphuric acid (H₂SO₄) and nitric acid (HNO₃).

These acids mix with rain, snow, or fog and fall as 'acid rain'.

Option (a) — CO₂ and nitrogen don't form strong acids.

CO₂ does form weak carbonic acid in rain, but this is natural and not what we call 'acid rain'.

Option (b) — CO and CO₂ are air pollutants but not the primary cause of acid rain.

Option (c) — ozone and CO₂ are not the primary cause either.

Option (d) correctly identifies nitrous oxide and sulphur dioxide as the culprits.

Why this was asked

Sulphur dioxide and nitrogen oxides from burning fossil fuels react with atmospheric water to form sulphuric and nitric acids that fall as acid rain.

The trap is that carbon dioxide forms only weak carbonic acid naturally, while SO₂ and NOₓ create the strong acids that define environmental acid rain.

Acid Rain Formation & Mechanism

Environment acid rain sulphur dioxide nitrous oxide

Acid Rain: Formation Process & Primary Pollutants

Must know

Acid rain forms when SO₂ and NOₓ react with water vapor to create sulfuric and nitric acids

Primary sources: coal-burning power plants and vehicle emissions

Good to know

Normal rain pH is 5.6, acid rain pH drops below 5.0

Damages forests, buildings, aquatic ecosystems, and human health

What is Acid Rain

Acid rain occurs when atmospheric sulfur dioxide (SO₂) and nitrogen oxides (NOₓ) chemically transform into acids and fall as precipitation. Unlike normal rain which is slightly acidic due to natural CO₂, acid rain has significantly lower pH and causes environmental damage.

Acid Rain Formation Process

%%{init: {"flowchart": {"wrappingWidth": 460}}}%%
flowchart TD
  s1["`**Emission**
**SO₂** and **NOₓ** released from fossil fuel burning`"]
  s2["`**Atmospheric Transport**
Gases rise and travel through atmosphere`"]
  s3["`**Chemical Reaction**
React with **water vapor** and **oxygen** to form acids`"]
  s4["`**Acid Formation**
**H₂SO₄** (sulfuric acid) and **HNO₃** (nitric acid) created`"]
  s5["`**Precipitation**
Acids mix with rain, snow, or fog and fall to earth`"]
  s1 --> s2
  s2 --> s3
  s3 --> s4
  s4 --> s5

Primary vs Secondary Pollutants

Pollutant

Type

Source

Role in Acid Rain

SO₂ (Sulfur Dioxide)

Primary

Coal burning, smelting

Forms sulfuric acid (H₂SO₄)

NOₓ (Nitrogen Oxides)

Primary

Vehicle emissions, power plants

Forms nitric acid (HNO₃)

H₂SO₄ (Sulfuric Acid)

Secondary

SO₂ + atmospheric reactions

Main component of acid rain

HNO₃ (Nitric Acid)

Secondary

NOₓ + atmospheric reactions

Secondary component of acid rain

Acid Rain Chemistry

SO₂ and NOₓ undergo atmospheric reactions to form the acids that make rain acidic
SO₂ and NOₓ undergo atmospheric reactions to form the acids that make rain acidic

Source: Fiveable — Acid Rain Formation and Effects | Environmental Chemistry ... · fiveable.me

Exam traps

CO₂ forms only weak carbonic acid - this is natural rain acidity, not harmful 'acid rain'

Carbon monoxide (CO) is a deadly gas but doesn't form acids in atmosphere

Ozone is a pollutant but doesn't directly cause acid rain formation

Don't confuse nitrous oxide (N₂O) with nitrogen dioxide (NO₂) - both are NOₓ gases that cause acid rain

Atmospheric Pollutants & Properties

Environment carbon dioxide carbon monoxide ozone

Major Atmospheric Pollutants: Sources & Environmental Effects

Must know

CO₂ is main greenhouse gas but only forms weak acids naturally

CO is toxic gas from incomplete combustion - deadly but doesn't form acids

O₃ at ground level is harmful pollutant, beneficial in stratosphere

Only SO₂ and NOₓ are primary acid rain precursors

Key Atmospheric Pollutants Comparison

Pollutant

Main Sources

Primary Effect

Role in Acid Rain

CO₂ (Carbon Dioxide)

Fossil fuel burning, respiration

Greenhouse effect, global warming

Forms weak carbonic acid naturally

CO (Carbon monoxide)

Incomplete combustion

Toxic - binds to hemoglobin

No role in acid rain

O₃ (Ozone)

Photochemical reactions

Respiratory damage, smog

No role in acid rain

SO₂ (Sulfur Dioxide)

Coal burning, oil refining

Acid rain formation

Primary acid rain precursor

NOₓ (Nitrogen Oxides)

Vehicle emissions, power plants

Acid rain and smog

Primary acid rain precursor

Why Other Options Are Wrong

Carbon dioxide naturally makes rain slightly acidic (pH 5.6) but this is normal, not harmful acid rain

Carbon monoxide is a silent killer that prevents oxygen transport but has no acid-forming properties

Ozone pollution creates respiratory problems and photochemical smog but doesn't generate acids

Nitrogen gas (N₂) is inert and makes up 78% of atmosphere - doesn't react to form acids

Exam traps

Don't assume all air pollutants cause acid rain - only SO₂ and NOₓ are primary causes

CO₂ is the biggest climate concern but NOT an acid rain creator

Ground-level ozone vs stratospheric ozone have opposite effects - ground level is harmful

Incomplete combustion produces CO; complete combustion produces CO₂

Environmental Impacts of Acid Rain

Environment

Acid Rain Impacts: Ecosystems, Infrastructure & Human Health

Must know

Kills forests by leaching nutrients from soil and damaging leaves

Makes lakes and rivers too acidic for fish and aquatic life

Good to know

Corrodes buildings, monuments, and metal structures

Worsens respiratory problems in humans

Acid Rain Impact Categories

# Acid Rain Impacts
## Forest Ecosystems
- Soil acidification
- Nutrient leaching
- Tree mortality
- Reduced growth
## Aquatic Systems
- Lake acidification
- Fish kills
- Algae changes
- Food chain disruption
## Built Environment
- Stone corrosion
- Metal damage
- Paint degradation
- Monument decay
## Human Health
- Respiratory issues
- Asthma worsening
- Skin irritation
- Eye problems

India's Acid Rain Concerns

Taj Mahal marble yellowing partly attributed to sulfur dioxide from nearby industries

Northeast India receives acid rain due to coal burning and industrial emissions

Thermal power plants using high-sulfur coal are major SO₂ contributors

Mumbai and Delhi show acid rain episodes during heavy industrial activity periods

Forest Damage

Acid rain leaches nutrients from soil and directly damages tree leaves and bark
Acid rain leaches nutrients from soil and directly damages tree leaves and bark

Source: USGS.gov — Forest affected by acid rain | U.S. Geological Survey · www.usgs.gov