Which of the following is/are the example/examples of chemical change? 1. Crystallization of sodium chloride 2. Melting of ice 3. Souring of milk Select the correct answer using the code given below.

Updated 11 Apr 2026 · From UPSC Prelims GS Paper I 2014, Q92

Contents10
UPSC Prelims GS2014Science and Technology
  1. A1 and 2 only
  2. B3 only
  3. C1, 2 and 3
  4. DNone
Show answer

Answer: (B) 3 only

Chemical change = a new substance is formed (irreversible, change in composition).

Physical change = only form/state changes (reversible, same substance).

(1) Crystallisation of NaCl — PHYSICAL change.

Salt molecules simply arrange into crystal structure; no new substance forms.

(2) Melting of ice — PHYSICAL change.

H2O stays H2O; only state changes from solid to liquid.

(3) Souring of milk — CHEMICAL change.

Bacteria convert lactose (milk sugar) into lactic acid through fermentation.

A completely new substance (lactic acid) is formed, and you can't reverse soured milk back to fresh milk.

Only statement 3 is a chemical change.

(Ref: NCERT Class 7 Science, Ch.6)

Why this was asked

Chemical changes create new substances that cannot be reversed (like milk souring into lactic acid), while physical changes only alter form or state of the same substance (like ice melting to water).

UPSC tests this fundamental concept because many students confuse processes that look dramatic (like crystallization) with actual chemical changes, when crystallization is just physical rearrangement of existing molecules.

Chemical vs Physical Changes

Science And Technology chemical change crystallization melting souring

Chemical vs Physical Changes: Definition & Key Differences

Must know

Chemical change = new substance forms, irreversible, composition changes

Physical change = same substance, only form/state changes, reversible

Souring of milk is chemical (lactose → lactic acid)

Crystallization and melting are physical changes

Core Concept

The key distinction lies in molecular composition. Chemical changes create entirely new substances with different properties, while physical changes only alter the appearance or state of the same substance.

Key Differences

Aspect

Chemical Change

Physical Change

New substance

Yes - different composition

No - same substance

Reversibility

Irreversible (difficult/impossible)

Reversible (easily undone)

Energy

Usually involves heat/light

May require energy but no new bonds

Examples

Burning, rusting, souring of milk

Melting, freezing, crystallization

Question Analysis

Crystallization of NaCl: Salt molecules just rearrange into crystal structure - same NaCl, different arrangement

Melting of ice: H₂O remains H₂O, only changes from solid to liquid state

Souring of milk: Bacteria convert lactose into lactic acid through fermentation - completely new substance

Exam traps

Trap: Crystallization sounds chemical but is physical - no new substance, just molecular arrangement

Trap: Any state change (solid↔liquid↔gas) is always physical, never chemical

Trap: Fermentation processes (souring, brewing) are always chemical changes

UPSC often tests irreversibility - ask 'can I easily get the original substance back?'

Common Chemical Changes

Science And Technology souring of milk

Common Chemical Changes: Processes & Examples

Must know

Fermentation: Bacteria convert sugars to acids (milk souring, alcohol production)

Oxidation: Substance combines with oxygen (rusting, burning)

Good to know

Decomposition: Complex substance breaks into simpler ones

Types of Chemical Changes

Type

Process

Example

New Substance Formed

Fermentation

Microorganisms convert sugars

Milk souring

Lactose → Lactic acid

Combustion

Substance burns in oxygen

Wood burning

Wood → CO₂ + H₂O + ash

Oxidation

Combines with oxygen

Iron rusting

Iron → Iron oxide (rust)

Decomposition

Complex breaks to simple

Food spoiling

Proteins → Ammonia + other compounds

Milk Souring Mechanism

Lactobacillus bacteria naturally present in milk convert lactose sugar

Lactose (milk sugar) breaks down into lactic acid through bacterial enzymes

Lactic acid gives sour taste and changes milk's pH from neutral to acidic

Process is irreversible - cannot convert soured milk back to fresh milk

Exam traps

Trap: Curdling vs souring - both are chemical but different processes

Trap: Pasteurization is physical (heating) but fermentation is chemical

Remember: Any biological process (digestion, respiration, fermentation) is usually chemical

Common Physical Changes

Science And Technology crystallization melting of ice

Common Physical Changes: State Changes & Molecular Rearrangement

Must know

State changes: Solid ↔ Liquid ↔ Gas (melting, freezing, boiling, condensation)

Crystallization: Dissolved substance forms crystals - same substance, new arrangement

All physical changes are easily reversible

Types of Physical Changes

Type

Process

Example

Reversibility

State Change

Solid ↔ Liquid ↔ Gas

Ice melting to water

Heat/cool to reverse

Crystallization

Dissolved particles form crystals

Salt crystallization

Dissolve in water again

Dissolution

Solid dissolves in liquid

Sugar in water

Evaporate water to get sugar

Sublimation

Solid directly to gas

Dry ice subliming

Cool gas back to solid

Crystallization Process

Salt molecules arrange themselves into regular, repeating 3D pattern

Same NaCl molecules - only their spatial arrangement changes

Can be reversed by dissolving crystals back in water

Energy required only to overcome intermolecular forces, not break chemical bonds

Exam traps

Trap: Crystallization involves energy but is still physical - no new bonds formed

Trap: Sublimation (solid→gas) is physical, decomposition (compound breaks) is chemical

Remember: If you can easily reverse the change, it's likely physical