Consider the following statements: 1. Other than those made by humans, nanoparticles do not exist in nature. 2. Nanoparticles of some metallic oxides are used in the manufacture of some cosmetics. 3. Nanoparticles of some commercial products which enter the environment are unsafe for humans. Which of the statements given above is/are correct?

Updated 11 Apr 2026 · From UPSC Prelims GS Paper I 2022, Q83

Contents17
UPSC Prelims GS2022Science and Technology
  1. A1 only
  2. B3 only
  3. C1 and 2
  4. D2 and 3
Show answer

Answer: (D) 2 and 3

The answer is (D) Statements 2 and 3.

Statement 1 is WRONG:

Nanoparticles DO exist naturally!

They're found in:

  • Interplanetary dust falling on Earth
  • Atmospheric dust
  • Volcanic ash
  • Ocean spray
  • Natural minerals (iron oxides, gold, silver nanoparticles)
  • Viruses are also nanoparticle-sized

They are NOT only man-made.

Statement 2 is CORRECT:

Metallic oxide nanoparticles are widely used in cosmetics:

  • Titanium dioxide and zinc oxide → used in sunscreens for UV protection
  • Silver nanoparticles → used for antimicrobial properties
  • Gold nanoparticles → used in anti-aging products

Statement 3 is CORRECT:

Nanoparticles from commercial products can be harmful when they enter the environment.

Workers who manufacture nanomaterials face occupational exposure, and consumers can be exposed during product use.

Due to their tiny size, nanoparticles can enter the body through skin, lungs, or ingestion and may cause toxic effects.

Why this was asked

Nanoparticles exist naturally in volcanic ash, ocean spray, and interplanetary dust - they are not only human-made.

Metallic oxide nanoparticles like titanium dioxide and zinc oxide are commonly used in sunscreens and cosmetics for UV protection.

The question tests whether students understand both natural occurrence and commercial applications of nanoparticles, not just their laboratory creation.

Natural Occurrence of Nanoparticles

Science And Technology nanoparticles exist in nature

Natural Nanoparticles: Sources & Examples

Must know

Nanoparticles exist naturally in multiple sources - not only man-made

Viruses are naturally occurring nanoparticle-sized entities

Good to know

Atmospheric dust and volcanic ash contain natural nanoparticles

Natural iron oxides, gold, silver can form nanoparticles

Context

Nanoparticles are particles between 1-100 nanometers in size. A common misconception is that they are purely synthetic - but nature produces them abundantly.

Natural Sources

Source

Type of Nanoparticles

Formation Process

Interplanetary dust

Silicates, metals

Space debris falling to Earth

Atmospheric dust

Mineral particles

Wind erosion, weathering

Volcanic ash

Silicate nanoparticles

Explosive volcanic eruptions

Ocean spray

Salt crystals

Wave action, evaporation

Natural minerals

Iron oxides, gold, silver

Geological weathering processes

Biological sources

Viruses, protein complexes

Natural biological processes

Question Context

Statement 1 in the PYQ claimed nanoparticles don't exist naturally - this is false. The trap was assuming nanoparticles are only industrial products.

Exam traps

Trap: Assuming nanoparticles are only synthetic/man-made

Remember: Viruses are natural nanoparticles (~20-300 nm)

Confusion: Don't mix up 'nanotechnology applications' with 'natural nanoparticle existence'

Nanoparticles in Cosmetics

Science And Technology metallic oxides cosmetics

Metallic Oxide Nanoparticles in Cosmetic Products

Must know

Titanium dioxide and zinc oxide nanoparticles used in sunscreens

Silver nanoparticles provide antimicrobial properties in cosmetics

Good to know

Gold nanoparticles used in anti-aging cosmetic products

Why Nanoparticles

Nanoparticles in cosmetics offer enhanced properties - better skin penetration, transparent appearance on skin, and improved effectiveness compared to larger particles.

Key Applications

Nanoparticle

Primary Use

Benefit

Common Products

Titanium dioxide (TiO₂)

UV protection

Blocks harmful UV rays

Sunscreens, BB creams

Zinc oxide (ZnO)

UV protection

Physical sunscreen agent

Sunscreens, foundations

Silver (Ag)

Antimicrobial

Prevents bacterial growth

Deodorants, creams

Gold (Au)

Anti-aging

Skin rejuvenation claims

Luxury face masks, serums

Advantages of Nano-size

Transparent finish - no white residue on skin unlike regular zinc oxide

Enhanced UV protection - better coverage due to smaller particle size

Improved stability - less likely to aggregate or settle

Better absorption - can penetrate skin layers more effectively

Exam traps

Correct: Statement 2 is true - metallic oxides ARE used in cosmetics

Remember: TiO₂ and ZnO are the most common nanoparticles in sunscreens

Don't confuse: Nano-cosmetics with food applications - different regulations apply

Environmental Safety of Nanoparticles

Science And Technology commercial products environment unsafe for humans

Nanoparticle Safety Risks & Environmental Impact

Must know

Nanoparticles from commercial products can be unsafe when entering environment

Tiny size allows nanoparticles to enter body through skin, lungs, ingestion

Good to know

Occupational exposure during manufacturing poses health risks to workers

Consumer exposure occurs during product use and disposal

Why Size Matters

Nanoparticles' extremely small size (1-100 nm) allows them to cross biological barriers that normally protect us - including cell membranes, blood-brain barrier, and lung-blood barrier.

Exposure Pathways

%%{init: {"flowchart": {"wrappingWidth": 460}}}%%
flowchart TD
  s1["`**Product Manufacturing**
Workers inhale nanoparticles during production`"]
  s2["`**Consumer Use**
Skin contact, inhalation during application`"]
  s3["`**Product Disposal**
Nanoparticles enter water systems, soil`"]
  s4["`**Environmental Accumulation**
Persistent nanoparticles build up in ecosystem`"]
  s5["`**Human Re-exposure**
Through food chain, water contamination`"]
  s1 --> s2
  s2 --> s3
  s3 --> s4
  s4 --> s5

Risk Categories

Exposure Route

Health Risk

Affected Population

Examples

Inhalation

Lung inflammation, respiratory issues

Factory workers, consumers

Spray products, powders

Skin penetration

Dermal toxicity, allergic reactions

Cosmetic users

Sunscreens, creams

Ingestion

Gastrointestinal effects

General population

Food packaging migration

Environmental

Ecosystem disruption

Wildlife, humans via food chain

Textile, paint industries

Question Context

Statement 3 correctly identifies that nanoparticles from commercial products entering the environment can be unsafe - this addresses both worker safety and environmental contamination concerns.

Exam traps

Correct: Statement 3 is true - commercial nanoparticles CAN be unsafe

Key point: Size enables barrier crossing - that's why they're more dangerous

Don't assume: All nanoparticles are equally dangerous - toxicity varies by material and exposure

Nanotechnology Fundamentals for UPSC

Science And Technology nanoparticles

Nanotechnology: Scale, Applications & UPSC Context

Must know

Nanoparticles are 1-100 nanometers in size

Size-dependent properties make nanoparticles behave differently than bulk materials

Good to know

Applications span medicine, cosmetics, electronics, energy, environment

Scale Understanding

1 nanometer = 10⁻⁹ meters. To visualize: if a marble were scaled up to Earth's size, a nanometer would be the size of the original marble. At this scale, materials exhibit unique properties different from their bulk form.

Major Applications

# Nanotechnology Applications
## Medicine
- Drug delivery
- Medical imaging
- Cancer treatment
- Antibacterial agents
## Cosmetics
- Sunscreens
- Anti-aging creams
- Antimicrobial products
- Color cosmetics
## Electronics
- Computer processors
- Memory devices
- Displays
- Sensors
## Environment
- Water purification
- Air filtration
- Catalysis
- Solar cells
## Materials
- Stronger composites
- Self-cleaning surfaces
- Coatings
- Textiles

Why Properties Change at Nano-scale

Increased surface area to volume ratio - more atoms at the surface react

Quantum effects become significant at nanoscale

Size-dependent optical properties - gold nanoparticles appear red/purple, not gold

Enhanced reactivity due to higher surface energy

Exam traps

Scale trap: Nano = 10⁻⁹, micro = 10⁻⁶ - don't confuse nanometer with micrometer

Property trap: Bulk gold is yellow, but gold nanoparticles can appear red/purple

Application trap: Same material can have different uses at nano vs bulk scale